https://scholars.lib.ntu.edu.tw/handle/123456789/183882
標題: | Single-step fabrication of phase-controllable nanocrystalline TiO(2) films for enhanced photoelectrochemical water splitting and dye-sensitized solar cells | 作者: | Lin, Chin-Jung Tu, Wen-Kai Kuo, Chih-Kang Chien, Shu-Hua |
關鍵字: | Dye-sensitized solar cell; Phase-controllable TiO2 film; Photoelectrochemical water splitting; Single-step fabrication | 公開日期: | 2011 | 起(迄)頁: | 4865-4869 | 來源出版物: | Journal of Power Sources | 摘要: | We introduce a single-step procedure for growing a phase-controllable bilayer-structured TiO2 film directly onto transparent conductive oxide glass by precipitation from hydrolysis of TiCl4 in acid solution containing sulfate ions. The obtained bilayer-structured film with anatase nanoparticles in the inner layer which provide high surface area, and an outer layer of larger rutile particles for incident light scattering. In both the water splitting and the dye-sensitized solar cells under AM 1.5 simulated solar light, the bilayer-structured film outperformed the single layer-structured films with either anatase or rutile TiO2 alone by at least 50%. © 2011 Elsevier B.V. All rights reserved. |
URI: | http://ntur.lib.ntu.edu.tw//handle/246246/239148 | DOI: | 10.1016/j.jpowsour.2010.12.077 | SDG/關鍵字: | Acid solutions; Anatase nanoparticles; Bi-layer; Dye-Sensitized solar cell; High surface area; Inner layer; Nanocrystalline TiO; Outer layer; Photoelectrochemical water splitting; Photoelectrochemicals; Rutile particles; Rutile TiO; Simulated solar light; Single layer; Single-step; Single-step fabrication; Structured films; Sulfate ion; TiO; Transparent conductive oxides; Water splitting; Dyes; Electrochemistry; Fabrication; Oxide minerals; Photoelectrochemical cells; Titanium dioxide; Solar cells |
顯示於: | 化學系 |
在 IR 系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。