https://scholars.lib.ntu.edu.tw/handle/123456789/403281
標題: | Ameliorating Interfacial Ionic Transportation in All-Solid-State Li-Ion Batteries with Interlayer Modifications | 作者: | Anirudha Jena Yedukondalu Meesala Shu-Fen Hu Ho Chang RU-SHI LIU |
公開日期: | 2018 | 出版社: | American Chemical Society ({ACS}) | 來源出版物: | ACS Energy Letters | 摘要: | Li-ion batteries (LIBs) are a class of electrochemical energy storage devices widely adapted for their versatile use. Commercialized liquid electrolyte-based batteries are developing various issues like explosions, limited energy density, and leakage. All-solid-state batteries (ASSBs) with Li-ion-containing solid electrolytes (SEs) can be a solution to these shortcomings. However, assembling ASSBs is a challenge due to the high interfacial resistance between the electrodes and SEs. In the current Review, we addressed the rising concern over the interfacial deterioration leading to high charge-Transfer resistance. A comprehensive discussion on the addition of buffer layers between the SE and electrodes is presented to improve interfacial stability. From polymer layers containing Li-salts with and without supporting fillers to amorphous oxides and metal coating, the interlayers ameliorate the ionic transport. Mutual compression and cosintering of SEs and electrodes can make a compact interface. Finally, the influence of morphology at the contacting surfaces is discussed. © 2018 American Chemical Society. |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/403281 | DOI: | 10.1021/acsenergylett.8b01564 | SDG/關鍵字: | Charge transfer; Composite films; Deterioration; Electrodes; Ions; Solid electrolytes; Solid state devices; All-solid state batteries; Compact interfaces; Contacting surfaces; Electrochemical energy storage devices; Interfacial resistances; Interfacial stabilities; Ionic transports; Liquid electrolytes; Lithium-ion batteries |
顯示於: | 化學系 |
在 IR 系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。