https://scholars.lib.ntu.edu.tw/handle/123456789/408646
標題: | A novel ionic liquid with stable radical as the electrolyte for hybrid type electrochromic devices | 作者: | Fan M.-S. Lee C.-P. Vittal R. Ho K.-C. |
關鍵字: | 2,2,6,6-tetramethyl-1-piperidinyloxy;Coloration efficiency;Electrochromic device;Ion-storage material;Ionic liquid | 公開日期: | 2017 | 卷: | 166 | 起(迄)頁: | 61-68 | 來源出版物: | Solar Energy Materials and Solar Cells | 摘要: | An ionic liquid (IL), 1-butyl-3-{2-oxo-2-[(2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl)amino]ethyl}-1H-imidazol-3-ium tetrafluoroborate (TILBF4), containing a stable radical, 2,2,6,6-tetramethyl-1-piperidinyl-oxy (TEMPO), was synthesized successfully. The TILBF4shows two distinctive properties having the characteristics of ion-storage and supporting electrolyte materials. In this study, a hybrid electrochromic device (ECD) with a high coloration efficiency based on this TILBF4and a poly(3,3-diethyl-3,4-dihydro-2H-thieno-[3,4-b][1,4]dioxepine) (PProDOT-Et2) thin film was proposed. The maximum absorbance of the PProDOT-Et2/TILBF4ECD was noticed at 590?nm upon applying the cell potential between ?1.0 and 1.0?V. The device exhibits a transmittance change (£GT) of 62.2% at 590?nm when being switched in the first transition, with short switching times of 4.0?s for bleaching and 3.6?s for coloring. A relatively high coloration efficiency (£b) of 983.0?cm2/C was achieved at 590?nm. Furthermore, the ECD maintained 98.0% of its initial £GT after consecutive operation for 1000 cycles between ?1.0 and 1.0?V. ? 2017 Elsevier B.V. |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/408646 | ISSN: | 09270248 | DOI: | 10.1016/j.solmat.2017.03.009 |
顯示於: | 化學工程學系 |
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