https://scholars.lib.ntu.edu.tw/handle/123456789/425147
標題: | Preparation of activated carbons from raw and biotreated agricultural residues for removal of volatile organic compounds | 作者: | HSING-CHENG HSI Horng, Richard S. Pan, Tai An Lee, Shin Ku |
公開日期: | 1-一月-2011 | 出版社: | TAYLOR & FRANCIS INC | 卷: | 61 | 期: | 5 | 起(迄)頁: | 543 | 來源出版物: | Journal of the Air and Waste Management Association | 摘要: | Activated carbons with diverse physical and chemical properties were produced from four agriculture residues, including raw barley husk, biotreated barley husk, rice husk, and pistachio shell. Results showed that with adequate steam activation (30-90 min, 50% H2O(g)/50% N2), activated carbons with surface areas between 360 and 950 m2 g-1 were developed. Further increases in the activation time destroyed the pore structure of activated carbons, which resulted in a decrease in the surface area and pore volume. Biotreated agricultural residues were found to be suitable precursors for producing mesoporous activated carbons. The oxygen content of activated carbons increased with increasing activation time. Results from X-ray photoelectron spectroscopy examination further suggested that H2O molecules react with the carbon surface, enhancing the deconvoluted peak area of carbonyl and carboxyl groups. Equilibrium adsorption of toluene indicated that the adsorption capacities increased with an increase in the inlet toluene concentration and a decrease in temperature. The adsorption isotherms were successfully fitted with Freundlich, Langmuir, and Dubinin- Radushkevich equations. Activated carbons derived from agricultural residues appear to be more applicable to adsorb volatile organic compounds at a low concentration and high-temperature environment. copy; 2011 Air & Waste Management Association. |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/425147 | ISSN: | 10962247 | DOI: | https://api.elsevier.com/content/abstract/scopus_id/79959586528 10.3155/1047-3289.61.5.543 |
顯示於: | 環境工程學研究所 |
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Preparation of Activated Carbons from Raw and Biotreated Agricultural Residues for Removal of Volatile Organic Compounds.pdf | 6.36 MB | Adobe PDF | 檢視/開啟 |
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