https://scholars.lib.ntu.edu.tw/handle/123456789/467515
標題: | A star-shaped conjugated molecule featuring a triazole core and diketopyrrolopyrrole branches is an efficient electron-selective interlayer for inverted polymer solar cells | 作者: | Chen, W.-J. Cheng, Y.-C. Kuo, D.-W. Chen, C.-T. Liu, B.-T. Jeng, R.-J. Lee, R.-H. RU-JONG JENG |
公開日期: | 2018 | 卷: | 8 | 期: | 55 | 起(迄)頁: | 31478-31489 | 來源出版物: | RSC Advances | 摘要: | A novel triazole-cored, star-shaped, conjugated molecule (TDGTPA) has been synthesized for use as an electron-selective interlayer in inverted polymer solar cells (PSCs). This star-shaped molecule comprised a triazole unit as the central core, 2,5-thienyl diketopyrrolopyrrole units as π-conjugated bridges, and tert-butyl-substituted triphenylamine units as both end groups and donor units. The inverted PSC had the device structure indium tin oxide/ZnO/TDGTPA/poly(3-hexylthiophene) (P3HT)/fullerene derivative (PC71BM)/MoO3/Ag. Inserting TDGTPA as the electron-selective layer enhanced the compatibility of the ZnO-based electron transport layer and the P3HT:PC71BM blend-based photoactive layer. The low energy of the lowest unoccupied molecular orbital (-3.98 eV) of TDGTPA was favorable for electron transfer from the photoactive layer to the ZnO layer, thereby enhancing the photovoltaic performance of the PSC. The photo-conversion efficiency of the device incorporating TDGTPA as the electron-selective layer was 15.8% greater than that of the corresponding device prepared without it. © The Royal Society of Chemistry. |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/467515 | DOI: | 10.1039/c8ra05360j | SDG/關鍵字: | Conjugated polymers; Electron transport properties; II-VI semiconductors; Indium compounds; Molecular orbitals; Molecules; Polymer solar cells; Stars; Synthesis (chemical); Tin oxides; Zinc oxide; Conjugated molecules; Diketopyrrolopyrroles; Electron transport layers; Inverted polymer solar cells; Lowest unoccupied molecular orbital; Photoactive layers; Photovoltaic performance; Star-shaped molecules; Solar cells |
顯示於: | 高分子科學與工程學研究所 |
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