https://scholars.lib.ntu.edu.tw/handle/123456789/598277
Title: | Recrystallized Perovskite Thin Film via Intense Pulse Light Sintering for Vertical Gradient Band Gap Perovskite Solar Cells | Authors: | Peng S.-Y Su T.-S Chen C.-A Chuang K.-W Wei T.-C Liao Y.-C. YING-CHIH LIAO |
Keywords: | gradient band gap;intense pulsed light;perovskite solar cell;phase separation;wet process;Energy gap;Film preparation;Perovskite;Phase separation;Semiconductor quantum dots;Sintering;Solar absorbers;Thin films;Gradient band gap;Intense pulsed light;Perovskite films;Perovskite thin films;Power conversion efficiencies;Preparation process;Pulse lights;Stacked layer;Vertical gradients;Wet process;Perovskite solar cells | Issue Date: | 2021 | Journal Volume: | 4 | Journal Issue: | 12 | Start page/Pages: | 14240-14248 | Source: | ACS Applied Energy Materials | Abstract: | A wet preparation process was developed to prepare vertical gradient perovskite film (MAPbBr3/MAPbBr3-xIx/MAPbI3) for solar cells. To avoid mutual dissolution, an MAPbBr3 quantum dot (QD) ink was directly inkjet printed on a spin-coated MAPbI3 film to create stacked perovskite layers (MAPbBr3 QD/MAPbI3). Intense pulse light (IPL) was used to sinter the stacked perovskite films. After the IPL sintering process, the grain size in the stacked layers significantly increased from 16 to 30 nm (MAPbBr3 QD) and from 123 to 538 nm (MAPbI3), respectively. Meanwhile, between the stacked layers, a mixed halide perovskite (MAPbBr3-xIx) film with a gradient was created. The IPL-sintered perovskite films remained stable without phase separation under 15 W/cm2 illimitation for 20 s. The gradient perovskite films were further assembled as an absorber layer in solar cell and exhibited a power conversion efficiency (PCE) of 17.06%. Moreover, the solar cell with vertical gradient showed good moisture stability and exhibited 80% PCE under relative humidity (RH) = 70% for 500 h. In summary, this process can create an interfacial gradient layer between light-absorbing materials and can be further applied to other material systems. ? 2021 American Chemical Society. |
URI: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85121577019&doi=10.1021%2facsaem.1c02989&partnerID=40&md5=608689edbbb9747b9d52a314fd681dd4 https://scholars.lib.ntu.edu.tw/handle/123456789/598277 |
ISSN: | 25740962 | DOI: | 10.1021/acsaem.1c02989 |
Appears in Collections: | 化學工程學系 |
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