https://scholars.lib.ntu.edu.tw/handle/123456789/611479
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Bien C.E. | en_US |
dc.contributor.author | Chen K.K. | en_US |
dc.contributor.author | Chien S.-C. | en_US |
dc.contributor.author | Reiner B.R. | en_US |
dc.contributor.author | Lin L.-C. | en_US |
dc.contributor.author | Wade C.R. | en_US |
dc.contributor.author | Ho W.S.W. | en_US |
dc.contributor.author | LI-CHIANG LIN | en_US |
dc.creator | Bien C.E.;Chen K.K.;Chien S.-C.;Reiner B.R.;Lin L.-C.;Wade C.R.;Ho W.S.W. | - |
dc.date.accessioned | 2022-05-24T06:10:38Z | - |
dc.date.available | 2022-05-24T06:10:38Z | - |
dc.date.issued | 2018 | - |
dc.identifier.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85054344948&doi=10.1021%2fjacs.8b06109&partnerID=40&md5=7837b4a56db02e3654d6b6697893a75d | - |
dc.identifier.uri | https://scholars.lib.ntu.edu.tw/handle/123456789/611479 | - |
dc.description.abstract | A Zn benzotriazolate metal-organic framework (MOF), [Zn(ZnO2CCH3)4(bibta)3] (1, bibta2- = 5,5′-bibenzotriazolate), has been subjected to a mild CH3CO2 -/HCO3 - ligand exchange procedure followed by thermal activation to generate nucleophilic Zn-OH groups that resemble the active site of α-carbonic anhydrase. The postsynthetically modified MOF, [Zn(ZnOH)4(bibta)3] (2?), exhibits excellent performance for trace CO2 capture and can be regenerated at mild temperatures. IR spectroscopic data and density functional theory (DFT) calculations reveal that intercluster hydrogen bonding interactions augment a Zn-OH/Zn-O2COH fixation mechanism. Copyright ? 2018 American Chemical Society. | - |
dc.relation.ispartof | Journal of the American Chemical Society | - |
dc.subject | Carbon dioxide | - |
dc.subject | Carbonic anhydrase | - |
dc.subject | Crystalline materials | - |
dc.subject | Density functional theory | - |
dc.subject | Hydrogen bonds | - |
dc.subject | Organometallics | - |
dc.subject | Trace elements | - |
dc.subject | Alpha-carbonic anhydrase | - |
dc.subject | Fixation mechanisms | - |
dc.subject | Hydrogen bonding interactions | - |
dc.subject | Ligand exchanges | - |
dc.subject | Metal organic framework | - |
dc.subject | Mild temperatures | - |
dc.subject | Spectroscopic data | - |
dc.subject | Thermal activation | - |
dc.subject | Zinc compounds | - |
dc.subject | benzotriazole | - |
dc.subject | biomimetic material | - |
dc.subject | carbon dioxide | - |
dc.subject | carbonate dehydratase | - |
dc.subject | metal organic framework | - |
dc.subject | triazole derivative | - |
dc.subject | zinc | - |
dc.subject | chemistry | - |
dc.subject | enzyme active site | - |
dc.subject | hydrogen bond | - |
dc.subject | isolation and purification | - |
dc.subject | molecular model | - |
dc.subject | synthesis | - |
dc.subject | Biomimetic Materials | - |
dc.subject | Carbon Dioxide | - |
dc.subject | Carbonic Anhydrases | - |
dc.subject | Catalytic Domain | - |
dc.subject | Hydrogen Bonding | - |
dc.subject | Metal-Organic Frameworks | - |
dc.subject | Models, Molecular | - |
dc.subject | Triazoles | - |
dc.subject | Zinc | - |
dc.title | Bioinspired Metal-Organic Framework for Trace CO2 Capture | en_US |
dc.type | journal article | en |
dc.identifier.doi | 10.1021/jacs.8b06109 | - |
dc.identifier.scopus | 2-s2.0-85054344948 | - |
dc.relation.pages | 12662-12666 | - |
dc.relation.journalvolume | 140 | - |
dc.relation.journalissue | 40 | - |
item.cerifentitytype | Publications | - |
item.fulltext | no fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_6501 | - |
item.openairetype | journal article | - |
item.grantfulltext | none | - |
crisitem.author.dept | Chemical Engineering | - |
crisitem.author.parentorg | College of Engineering | - |
顯示於: | 化學工程學系 |
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