https://scholars.lib.ntu.edu.tw/handle/123456789/625226
Title: | A water-soluble corannulene with highly efficient ROS production | Authors: | Cai C Huang J.-J Sano K Zhu Y Zhang Y Wu Q Zhu B Ishida Y SHYH-CHYANG LUO Lin H.-A. |
Keywords: | Buckybowl; Corannulene; Curved polyaromatic hydrocarbon; Reactive oxygen species; Singlet oxygen | Issue Date: | 2022 | Journal Volume: | 281 | Source: | Materials Chemistry and Physics | Abstract: | Under light irradiation, corannulene produces toxic reactive oxygen species (ROS), which have potential applications for disease treatment in biological systems. However, no effective functionalization strategy for endowing corannulene with high water solubility and efficient ROS production ability at the same time currently exists. Herein, a new corannulene derivative (EGph-Cora) with five hydrophilic rotating groups, which improve the solubility of the molecule in water and reduce its molecular aggregation, is presented. EGph-Cora exhibits not only high photostability but also high Type I and Type II ROS quantum yields (0.2 and 0.99, respectively). © 2022 Elsevier B.V. |
URI: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85125221583&doi=10.1016%2fj.matchemphys.2022.125885&partnerID=40&md5=5014efcb521dbcfa8d0abfdf6c4b24e2 https://scholars.lib.ntu.edu.tw/handle/123456789/625226 |
ISSN: | 02540584 | DOI: | 10.1016/j.matchemphys.2022.125885 | SDG/Keyword: | Oxygen; Buckybowls; Corannulene; Curved polyaromatic hydrocarbon; Disease treatment; Functionalizations; Light irradiations; Polyaromatic hydrocarbons; Reactive oxygen species; Singlet oxygen; Watersoluble; Solubility |
Appears in Collections: | 材料科學與工程學系 |
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