https://scholars.lib.ntu.edu.tw/handle/123456789/637564
DC 欄位 | 值 | 語言 |
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dc.contributor.author | Atayde, Eduardo C. | en_US |
dc.contributor.author | Matsagar, Babasaheb M. | en_US |
dc.contributor.author | Wang, Yu Cheng | en_US |
dc.contributor.author | KEVIN CHIA-WEN WU | en_US |
dc.date.accessioned | 2023-12-06T02:28:32Z | - |
dc.date.available | 2023-12-06T02:28:32Z | - |
dc.date.issued | 2024-01-05 | - |
dc.identifier.issn | 0926860X | - |
dc.identifier.uri | https://scholars.lib.ntu.edu.tw/handle/123456789/637564 | - |
dc.description.abstract | Hydroxyalkylation-alkylation (HAA) reaction is a type of C-C coupling technique utilized in the production of furan oligomers, which are potential biofuel precursors. In this study, we present the first application of an acidic MOF, Sulfated MOF-808, in catalyzing the HAA reactions of a series of furan oligomers with high yield and selectivity. Specifically, we focused on the optimization of the HAA between 5-methylfurfural (5-MFUR) and 2-methylfuran (2-MF) by varying different reaction conditions, which afforded a quantitative yield reaching 97% while preventing the self-condensation of 2-MF. The catalyst was also found to be recyclable and can be reused without significant loss in its activity. Lastly, we extended the substrate scope to include benzene-based electrophiles, thereby further proving the versatility of the Sulfated MOF-808 catalyst in the HAA reactions of a variety of starting materials. | en_US |
dc.relation.ispartof | Applied Catalysis A: General | en_US |
dc.subject | Biomass | Catalysis | Furan oligomers | Hydroxylalkylation/alkylation reactions | Metal-organic frameworks | en_US |
dc.title | MOF-catalyzed hydroxyalkylation-alkylation reaction for the controlled synthesis of furan oligomers | en_US |
dc.type | journal article | en |
dc.identifier.doi | 10.1016/j.apcata.2023.119492 | - |
dc.identifier.scopus | 2-s2.0-85176322756 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/85176322756 | - |
dc.relation.journalvolume | 669 | en_US |
item.openairetype | journal article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_6501 | - |
item.fulltext | no fulltext | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
crisitem.author.dept | Chemical Engineering | - |
crisitem.author.orcid | 0000-0003-0590-1396 | - |
crisitem.author.parentorg | College of Engineering | - |
顯示於: | 化學工程學系 |
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