Conversion of Diamino-Substituted Carbene Complexes into the Isocyanide by Acylation
Resource
Organometallics 17 (10): 1937-1940
Journal
Organometallics
Journal Volume
17
Journal Issue
10
Pages
1937-1940
Date Issued
1998
Date
1998
Author(s)
Abstract
A carbene transfer reaction between transition-metal complexes is reported. Carbene complexes of Pd(II), Pt(II), Rh(I), and Au(I) are formed via the reaction = W, Mo, Cr; R = Et, allyl) with (PhCN)2PdCl2, (PhCN)2PtCl2, [(CO)2RhCl]2, and (Me2S)AuCl. The complexes prepared in high yields via a carbene transfer pathway. The X-ray structures (4) are reported.
SDGs
Type
journal article
File(s)![Thumbnail Image]()
Loading...
Name
199.pdf
Size
123.99 KB
Format
Adobe PDF
Checksum
(MD5):54ddcc8c4b352bd3618cc33216a5e861