The Amidinium-Carboxylate Salt Bridge as a Proton-Coupled Interface to Electron Transfer Pathways
Resource
Angewandte Chemie International Edition in English 36 (19): 2124-2127
Journal
Angewandte Chemie International Edition in English
Journal Volume
36
Journal Issue
19
Pages
2124-2127
Date Issued
1997
Date
1997
Author(s)
Abstract
An unusually slow electron transfer takes place in the porphyrinato complex 1 (M = Ni, Zn). The rate of this proton-coupled electron transfer is influenced by a salt bridge in which benzoate ions are bound to the amidinium group, even in solvents with a high dielectric constant, such as DMSO.
Type
journal article
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