Solid-State Supramolecular Organization of Supermolecules into a Truly Molecular Zeolite
Resource
Angewandte Chemie International Edition 42 (26): 2999-3001
Journal
Angewandte Chemie International Edition
Pages
2999-3001
Date Issued
2003
Date
2003
Author(s)
Shiu, Kom-Bei
Lee, Hong-Chan
Lee, Gene-Hsiang
Ko, Bao-Tsan
Wang, Yu
Lin, Chu-Chieh
Abstract
Letting out the guests: The hexagonal closest packing of discrete triangular-tube-shaped organometallic supermolecules of eclipsed-[{Ru2(CO)4(PPh3)2}(�g-4,4��-O2CC6H4C6H4CO2)]3 in the solid state (see picture) permits the production of a microporous material that is not only thermally stable up to 181 �XC, but also allows diffusion at room temperature of molecular guests without the framework collapsing. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2003/z51149_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Type
journal article
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