Processing and microstructure of Nano-Mo/Al2O3 composites from MOCVD and fluidized bed
Journal
Nanostructured Materials
Journal Volume
11
Journal Issue
8
Pages
1361-1377
Date Issued
1999
Date
1999
Author(s)
Abstract
The process utilizing metal-organic chemical vapor deposition (MOCVD) was conducted in a fluidized Al2O3 powder bed for the preparation of nano-Mo ceramic composites. During the process, Mo species were deposited in fine Al2O3 ceramic powder using a pyrolysis of Mo carbonyl. The composition and crystallinity of the intermediate phases of Mo2CxOy, and the microstructure of the coated particles and coated layer were analyzed using XRD/SEM/TEM techniques. The granulated powder was then treated by H2 reduction, pressureless sintering or hot-pressing in a vacuum, which could achieve densities better than 99% T.D. The densification, wear, and microstructural properties of the dense nano Mo-composites were then investigated and discussed. It is seen that the nano-inclusion of Mo grains inhibited the grain growth of the alumina matrix, which had a mean grain size of either 4.9 μm or 1.2 μm, as the volume fraction of Mo increased from 0 vol% to 5 vol%. The wear resistance of the nano-Mo/Al2O3 was approximately 2 times better than that of pure Al2O3. Through an understanding of the pyrolysis of Mo(CO)6 and grain growth kinetics of Mo-species growth kinetics, the morphology and size of the Mo grains in ceramic composites can be modified.
SDGs
Other Subjects
Alumina; Composition; Fluidized beds; Metallographic microstructure; Metallorganic chemical vapor deposition; Molybdenum; Pyrolysis; Reduction; Scanning electron microscopy; Sintering; Transmission electron microscopy; X ray diffraction analysis; Carbonyl; Intermediate phases; Nanostructured materials
Type
journal article
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