Solvolyses of substituted naphthylmethyl tosylates. Importance of the extent of solvation on delocalized cationic transition states on the correlation of solvolytic reactivities
Resource
Tetrahedron Letters 33 (23): 3327-3330
Journal
Tetrahedron Letters
Journal Volume
33
Journal Issue
23
Pages
3327-3330
Date Issued
1992
Date
1992
Author(s)
Abstract
Grunwald-Winstein correlation analyses of solvolytic reactivities for 2, 2, 2-trifluoro-1-napthyethyl tosylates 2-4 were found to show linear realtionships with that of 2, 2-dimethyl-1-napthylpropyl tosylate 5 but not with that of 2, 2-dimethyl-1-phenylpropyl or adamantyl tosylate, from which the importance of solvation of delocalized cationic transition state could be demonstrated. © 1992.
Type
journal article
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