Fluorinated polythiophenes with ester side chains for boosting the V and efficiency in non-fullerene polymer solar cells
Journal
Polymer
Journal Volume
326
Start Page
128336
ISSN
0032-3861
Date Issued
2025-05-09
Author(s)
Li-Yun Su
Yi-Ling Zhou
Yu-Ting Chen
Guan-Lin Chen
Kai-Wei Tseng
Nikita Tukachev
Andriy Zhugayevych
Sergei Tretiak
Abstract
As the power conversion efficiency (PCE) of organic photovoltaics (OPVs) approximates the 19 % threshold, wide bandgap (WBG) polythiophenes (PTs) have gained increasing attention due to their simple chemical structures and ease of synthesis, making them promising candidates for large-scale production. However, the benchmark polymer poly(3-hexylthiophene) (P3HT) is limited by its high-lying HOMO energy level, which restricts the open-circuit voltage (VOC) in solar cells. In this study, we introduce a novel series of PT derivatives (PDC8-T, PDC8-3T, PDC16-3T, and PDC16-3T-2F) featuring ester side chains designed to fine-tune electronic properties through a streamlined three-step synthesis. Additionally, we incorporated a π-spacer to reduce steric hindrance and elongated alkyl side chains to improve solubility and processability. Compared to P3HT, these PT derivatives demonstrate a significant reduction in HOMO energy levels, lowering by approximately 0.3–0.4 eV. Among them, PDC16-3T-2F—with fluorine atom substitution—achieves the lowest HOMO energy level, induces a coplanar molecular conformation, and enhances polymer aggregation behavior. We evaluated these PT derivatives in inverted non-fullerene bulk-heterojunction (NFA BHJ) OPVs. The PDC8-3T device showed a relatively low PCE of 0.69 %, with a VOC of 0.76 V, a short-circuit current density (JSC) of 3.32 mA/cm2, and a fill factor (FF) of 27.3 %. In contrast, the PDC16-3T-2F device achieved an impressive PCE of 7.21 %, with a VOC of 0.85 V, a JSC of 14.60 mA/cm2, and an FF of 58.4 %. This remarkable improvement is attributed to the fluorine substitution, which not only enhances molecular orientation but also downshifts the HOMO energy level and further boosts the VOC. Hence, these molecular design strategies have led to a fibrillar bicontinuous interpenetrating network with optimal nanoscale phase separation within the active layer.
Subjects
Ester side group-based polythiophene
Fluorination
Non-fullerene polymer solar cells
SDGs
Publisher
Elsevier BV
Type
journal article