Synthesis and electrochromism of novel organosoluble polyarylates bearing triphenylamine moieties
Journal
Journal of Polymer Science, Part A: Polymer Chemistry
Journal Volume
45
Journal Issue
10
Pages
2004-2014
Date Issued
2007
Author(s)
Abstract
A series of novel aromatic polyarylates with triphenylamine units in the main chain and as the pendent group were prepared from the dicarboxylic acid monomer, N,N-bis(4-carboxyphenyl)-N′, N′-diphenyl-1,4- phenylenediamine (1), and various bisphenols. These polyarylates were amorphous and readily soluble in common organic solvents. They had excellent levels of thermal stability associated with moderately high Tg values (182-263 °C). These polymers exhibited strong UV-vis absorption bands at 357-360 nm in toluene solution and the photoluminescence spectra showed maximum bands around 493-503 nm in the green region. The hole-transporting and electrochromic properties were examined by electrochemical and spectro-electrochemical methods. Cyclic voltammograms of the polyarylates exhibited two reversible oxidation redox couples in acetonitrile solution at Eonset 0.77-0.79 V and 1.12-1.14 V, respectively. The typical polymer 3b film revealed good stability of electrochromic characteristics, with color change from colorless to green and blue at applied potentials ranging from 0.00 to 1.24 V. These anodically polymeric electrochromic materials not only showed excellent reversible electrochromic stability with good green coloration efficiency (CE = 159 cm 2/C) and blue coloration efficiency (CE = 154 cm2/C) but also exhibited high contrast of optical transmittance change (ΔT%), 54% in 895 nm for green color and up to 84% in 595 nm for blue color. After over 100 cyclic switches, the polymer films still exhibited excellent stability of electrochromic characteristics. © 2007 Wiley Periodicals, Inc.
Type
journal article