A new sol-gel route using inorganic salts for synthesizing barium magnesium tantalate ceramics
Resource
Materials Letters 31 (3-6): 271-274
Journal
Materials Letters
Journal Issue
31
Pages
271-274
Date Issued
1997
Date
1997
Author(s)
Tsai, Chien-Cheng
Abstract
A new sol-gel process using inorganic salts instead of metal alkoxides has been successfully developed for preparing Ba(Mg1/3Ta2/3)O3. Pure Ba(Mg1/3Ta2/3)O3 polycrystalline powders were obtained by calcining the derived precursors at 1100°C. The particle size of the obtained fine particles was around 0.1 μm. The ordering parameter of the sintered Ba(Mg1/3Ta2/3)O3 was found to strongly depend on the calcination temperatures. Sintering the 1200°C-calcined powders at 1690°C resulted in the ordering parameter to be 0.82, which is greater than that obtained in the conventional solid-state reaction. The improvement in the ordering parameter is attributed to the enhanced compositional homogeneity in the powders prepared via the sol-gel process.
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Type
journal article
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