Formation of isocyanide complexes via acylation of diaminocarbene complexes
Resource
Journal of Organometallic Chemistry 561 (1-2): 153-155
Journal
Journal of Organometallic Chemistry
Journal Volume
561
Journal Issue
1-2
Pages
153-155
Date Issued
1998
Author(s)
Cho, Jian-Yang
Chen, Chi-Li
Hsieh, Tung-Ying
Kiang, Fu-Mei
Lee, Gene-Hsiang
Peng, Shie-Ming
Abstract
Treatment of cyclic diaminocarbene tungsten complexes (CO)5W=CNRCH2CH2NH [R=Ph, Et] with acylating agents resulted in the formation of isocyanide complexes via the cleavage of C-N bond. Crystal structure of (CO)5WCN(CH2)2N(Ph)COPh 2a was determined.
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Type
journal article
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