The Synthesis of Molecular Clip Dimers
Date Issued
2008
Date
2008
Author(s)
Lin, You-Han
Abstract
We have reported the synthesis of a molecular clip with TTF (tetrathiafuvalene) as the sidewalls and its binding behavior towards a macrocycle in which an electron-deficient pyridinium unit was present. This macrocycle/molecular-clip complex functions as a quadruply controllable molecular switch for the addition and removal of heat, metal ions, protons, electrons. o extend the application of this molecular clip system, we plan to synthesize new molecular clips that present suitable functionalities as their “feet” which are capable to connect with metal. These molecular clip dimer could creat a new host-guest system compared to the traditional rotaxane and catenane.
Subjects
Molecular Clip
Type
thesis
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