The Synthesis and Supramolecule Architecture of Truxene Based Derivatives
Date Issued
2009
Date
2009
Author(s)
Kao, Min-Tzu
Abstract
In our previous contribution, we reported a unique 3D skeleton based onruxene moiety. The success of synthesizing such skeleton provides us withonvenience to realize the structural diversity of 3D derivatives through orthogonallynd distinguishably modifiable sites. As a result, such a 3D structure would offerarious derivatives with diverse functionalities. Herein, we utilize this 3Dunctionalized “body＂ (a covalent template) to couple with suitable planar “caps＂o achieve quantitative formation of C3 symmetrical nanocages. Furthermore, weunctionalized this central core to achieve the 3D architecture organogelators. To the best of our knowledge, there is no organogelator based on 3D skeleton design.herefore, the microstructure and the gelation mechanism of these gelators are very intriguing. And then we developed this 3D structure as a “molecular claw＂,xpecting it could have good interaction with bulky ball.
Subjects
cage
organogel
supramolecule
truxene
Type
thesis
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