Cyclopropenation of organometallic vinylidene complexes

Resource
Journal of Organometallic Chemistrys 617-618: 141-147
Journal
Journal of Organometallic Chemistry
Journal Volume
617-618
Pages
141-147
Date Issued
2001
Author(s)
Lin, Ying-Chih
DOI
URI
Abstract
The chemistry of metal cyclopropenyl complexes derived from deprotonation of cationic ruthenium vinylidene complexes is reviewed. Such a metal coordinated cyclopropenyl ligand can be used for the preparation of heterocyclic compounds. The chemical reactivity of cyclopropenyl complexes is influenced by the nature of substituents on the three-membered ring and by the nature of ancillary ligand around the metal centers. © 2001 Elsevier Science B.V.
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