Structure and characterization of the first metal complex of dithiaporphyrin: Ru(s2TTP)Cl2
Journal
Inorganic Chemistry
Journal Volume
40
Journal Issue
26
Pages
6845-6847
Date Issued
2001
Author(s)
Abstract
The ruthenium complex of tetratolyldithiaporphyrin was synthesized and characterized. The solid-state structure demonstrates that, in order to accommodate ruthenium metal in the central core, the thiophene rings tilt away from the dithiaporphyrin core and coordinate to metal in an n1-pyrimidal side-on fashion.
Type
journal article