The first one-dimensional coordination polymer containing O-H···F-Ni hydrogen bonding: Crystal structure of [Ni3(dpa)4F2] [Ni3(dpa)4(H2 O)2](BF4)2 · 2CH3OH
Journal
Inorganic Chemistry Communications
Journal Volume
6
Journal Issue
1
Pages
1-4
Date Issued
2003
Author(s)
Abstract
The one-dimensional coordination polymer, [Ni3(dpa)4F2][Ni3 (dpa)4(H2O)2](BF4)2 · 2CH3OH (dpa- = bis(2-pyridyl)amido ligand), has been constructed. The title complex crystallizes in the triclinic system, space group P, with a= 11.5966(1), b = 19.5609(2), c = 20.1509(2) Å, α = 79.5672(4), β = 75.4196(4), γ = 76.2199(5)°, Z = 2. The rare type hydrogen bonding of O-H⋯F-Ni links the two kinds of the trinickel metal string complexes as building blocks. © 2002 Elsevier Science B.V. All rights reserved.
Type
journal article