On the Use of Triethylamine Hydroiodide as a Supporting Electrolyte in Dye-Sensitized Solar Cells
Resource
Solar Energy Materials and Solar Cells 91 (15-16): 1432-1437
Journal
Solar Energy Materials and Solar Cells
Journal Volume
91
Journal Issue
15-16
Pages
1432-1437
Date Issued
2007
Date
2007
Author(s)
Abstract
For the first time, the application of a molten salt, triethylamine hydroiodide (THI), as a supporting electrolyte was investigated for the dye-sensitized solar cells (DSSCs). Titanium dioxide (TiO2) electrode was modified by incorporation of high- and low-molecular weight poly(ethylene glycol) along with TiO2 nanoparticles of two different sizes (300 nm (30 wt%) and 20 nm (70 wt%)). The highest apparent diffusion coefficient (D) of 8.12×10-6 cm2 s-1 was obtained for I- (0.5 M of THI) from linear sweep voltammetry (LSV). Short-circuit current density (Jsc) increases with the concentration of THI whereas open-circuit potential (Voc) remains the same. Optimum Jsc (19.28 mA cm-2) and Voc (0.7 V) with a highest conversion efficiency (η) of 8.45% were obtained for the DSSC containing 0.5 M of THI/0.05 M I2/0.5 M TBP in CH3CN. It is also observed that the Jsc and η of the DSSC mainly relates with the D values of I- and charge-transfer resistances such as Rct1 and Rct2 operating along Pt/TiO2 electrolyte interface, obtained from LSV and electrochemical impedance spectroscopy (EIS). For comparison, tetraethylammonium iodide (TEAI) and LiI were also selected as supporting electrolytes. Though both the THI and TEAI have similar structures, replacement of one methyl group by hydrogen improves the efficiency of the DSSC containing the former electrolyte. Further, the DSSC containing THI exhibits higher Jsc and η than LiI (7.70%), from which it is concluded that THI may be used as an efficient and alternative candidate to replace LiI in the current research of DSSCs. © 2007 Elsevier B.V. All rights reserved.
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