Donor-acceptor organic sensitizers assembled with isoxazole or its derivative 3-oxopropanenitrile
Journal
Tetrahedron
Journal Volume
66
Journal Issue
23
Pages
4223-4229
Date Issued
2010
Author(s)
Li, Yi-Tsung
Chen, Chao-Ling
Hsu, Yu-Yen
Hsu, Hui-Chu
Chi, Yun
Chen, Bo-So
Liu, Wei-Hsin
Lai, Cheng-Hsuan
Lin, Tsung-Yi
Abstract
A series of new donor-acceptor organic sensitizers LJ5-LJ7 assembled with isoxazole or its derivative 3-oxopropanenitrile was synthesized and used in dye-sensitized solar cells to study the effect of both π-spacers and anchoring groups on device performance. X-ray crystal structure analyses show planar arrangement of dithiophene and isoxazole fragments, providing an excellent π conjugation and hence the large electronic coupling between the triphenylamine donor and electron acceptor units. For the DSSC applications, the derived photophysical and photovoltaic properties revealed a lower η value of 1.06% (LJ7) and 2.41% (LJ5), and 3.30% (LJ7) for the dyes with rhodanine-3-acetic acid, cyanoacetyl group, and vinyl cyanoacetic acid as the anchor. Electrochemical impedance spectroscopy was used to determine the interfacial charge transfer process occurring in solar cells that employed different dyes. Crown Copyright © 2010.
SDGs
Other Subjects
3 oxopropanenitrile; acetic acid derivative; dye; isoxazole; isoxazole derivative; thiophene; unclassified drug; article; crystal structure; device; dye sensitized solar cell; electric current; photochemistry; priority journal; sensitization; structure analysis; synthesis
Type
journal article