Self-Assembly of Octarhenium-Based Neutral Luminescent Rectangular Prisms
Resource
Inorganic Chemistry 42 (16): 4795-4797
Journal
Inorganic Chemistry
Journal Volume
42
Journal Issue
16
Pages
4795-4797
Date Issued
2003
Date
2003
Author(s)
Manimaran, Bala.
Thanasekaran, P.
Rajendran, T.
Liao, Rong-Tang
Liu, Yen-Hsiang
Lee, Gene-Hsiang
Rajagopal, S.
Lu, Kuang-Lieh
Abstract
Self-assembly of rhenium-based nanoscale rectangular prismatic boxes has been achieved in quantitative conversion. The fac-rhenium corner provided three mutually perpendicular coordination sites and served as a good candidate for the construction of 3-D boxes. These are the first Re-based, neutral, luminescent prisms of M(8)L(2)L'(8) type that has been characterized crystallographically. Their luminescent properties and molecular recognition capabilities make these molecular prisms interesting supramolecules.
Type
journal article
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