Homonuclear dirhenium complex bridged by CO2: Molecular structure of a rhenium dimer bridged by CO2 and a rhenium chloride complex
Resource
Journal of Organometallic Chemistry 467 (2): C6-C8
Journal
Journal of Organometallic Chemistry
Journal Volume
467
Journal Issue
2
Date Issued
1994
Author(s)
Abstract
A mononuclear complex (CO)3ReL2Cl (1a) (L = NH2CHMe2) and a dinuclear CO2 complex (CO)3L2Re(μ,η1,η1-CO2)Re(CO)4L (2) are prepared from the reaction of a carbamoyl complex, (CO)4ReL(CONHCHMe2) with H2O in CHCl3. The coupling of a proposed intermediate (CO)4LReCOOH with 1a is a viable process for the formation of complex 2. The structures of (CO)3ReL2Cl (1b) (L= NH2CH2CH=CH2) and 2 have been established by X-ray diffraction. © 1994.
SDGs
Type
journal article