Large-Scale Uniform Two-Dimensional Hexagonal Arrays of Gold Nanoparticles Templated from Mesoporous Silica Film for Surface-Enhanced Raman Spectroscopy
Journal
Journal of Physical Chemistry C
Journal Volume
120
Journal Issue
42
Pages
24382-24388
Date Issued
2016
Author(s)
Abstract
A good surface-enhanced Raman spectroscopy (SERS) substrate requires precise control of the enhancement factor in large area which may be achieved with large-scale hot spot engineering. Here, we present a facile method for synthesizing 2-D hexagonally patterned gold nanoparticle arrays on centimeter-sized substrates of mesoporous silica thin films with vertical nanochannels by chemical reduction. Scanning electron microscopy images showed densely packed gold nanoparticles directly anchored on the openings of vertical mesopores (∼5 nm) leading to 2 nm nanogaps between the gold nanoparticles. The gold nanoparticle arrays showed red-shifted localized surface plasmon resonance spectra due to strong couplings between close-packed gold. The dense on-substrate 2 nm plasmonic nanogaps lead to highly enhanced local electric field and excellent macroscopic uniformity in SERS.
SDGs
Publisher
American Chemical Society
Type
journal article