Coordination polymers constructed from [Mn(N)(CN)4] 2-: Synthesis, structures, and magnetic properties
Journal
European Journal of Inorganic Chemistry
Journal Issue
1
Pages
158-163
Date Issued
2008
Author(s)
Abstract
Abstract The dimetallic complexes [{Ni(cyclen)}{Mn(N)(CN) 4 } · CH 3 OH] n (cyclen = 1,4,7,10‐tetraazacyclododecane) ( 1 ), [{Cu(cyclen)}{Mn(N)(CN) 4 }] n ( 2 ), and [{Mn(5,5′‐Me 2 salen)} 2 {Mn(N)(CN) 4 } · CH 3 OH] n [5,5′‐Me 2 salen = N , N′ ‐bis(5,5′‐dimethylsalicylidene)‐ o ‐ethylenediimine] ( 3 ) have been synthesized and structurally characterized. Compounds 1 and 2 have one‐dimensional chain structures, while compound 3 has a two‐dimensional sheet‐like network structure. Magnetic studies of 1 and 3 show that there is no significant magnetic coupling between the paramagnetic metal centers. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
Type
journal article