Norbornadiene as an Efficient Hydrogen Scavenger for the Palladium-Catalyzed Conversion of Hydrosilanes to Alkoxysilanes
Resource
Journal of Organic Chemistry 67 (19): 6860-6862
Journal
Journal of Organic Chemistry
Journal Volume
67
Journal Issue
19
Pages
6860-6862
Date Issued
2002
Date
2002
Author(s)
Sudhakar, Sundarraj
Abstract
A palladium-catalyzed mild and efficient method for the alcoholysis of hydrosilanes containing a C=C bond in the presence of norbornadiene (NBD) is reported. The highly strained NBD acts as a hydrogen scavenger, which abstracts the hydrogen produced during the process, protecting the C=C bond from being hydrogenated.
Type
journal article
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