Rhodizonate metal complexes with a 2D chairlike M6 metal-organic framework: [M(C6O6)(bpym)(H2O)]·nH 2O
Journal
Angewandte Chemie - International Edition
Journal Volume
43
Journal Issue
34
Pages
4507-4510
Date Issued
2004
Author(s)
Abstract
Two transition-metal rhodizonate complexes, [M(C6O6)(bpym)(H2O)]⋅n H2O (M=Cd, n=1; M=Mn, n=2; bpym=2,2′-bipyrimidine), are reported. Both the rhodizonate and bpym ligands are bis-bidentate ligands (see the Cd example depicted) which chelate the metal ions, thus forming a novel 2D chairlike M6 metal–organic framework.
Type
journal article