Lead Tetraacetate Oxidation on Caryachine, a Phenolic Pavine
Journal
Journal of the Chinese Chemical Society
Journal Volume
44
Journal Issue
4
Pages
391-394
Date Issued
1997
Author(s)
Chiou C.-M.
Abstract
Abstract Lead tetraacetate oxidation on caryachine, a pavine alkaloid possessing a phenolic group at the position para to the N ‐methine, in dichloromethane yielded four products — 10‐acetoxy‐ O ‐acetyl‐caryachine, 10‐acetoxycaryachine, 7‐acetoxy‐ O ‐acetylcaryachine and (6 S , 11 R , 12 R )‐11‐acetoxy‐ O ‐acetyl‐caryachine. The reaction took place via adoption of an acetoxy group at a position majorly ortho to the phenolic group, but very minorly at the desired benzylic position para to the phenolic group.
SDGs
Type
journal article