Effect of Dealloying Time and Post-Annealing on the Surface Morphology and Electrocatalytic Behavior of Nanoporous Copper Films for CO2Reduction Reaction
Journal
Journal of the Electrochemical Society
Journal Volume
168
Journal Issue
12
Date Issued
2021
Author(s)
Abstract
Electrocatalytic reduction reaction of CO2 (CO2RR) is one of the promising routes to mitigate global warming via transforming greenhouse gas into valuable chemical feedstocks. By adding proper electrocatalysts, such as nanoporous copper (NPC) with an average ligament size of 37 ± 6 nm, hydrocarbons could be produced at a relatively low overpotential. As the dealloying time increased to 156 h, the NPC was transformed into CuO nanosheet structure, which yielded larger electrochemical surface area (ECSA) and current density than the as-prepared NPC films. However, the Faraday efficiency (FE) of the major conversion product, formic acid (HCOOH), decreased from 29 to 8% when the nanosheet structure was used as electrocatalyst. On the other hand, the surface morphology of the NPC films remained similar while the average ligament size increased from 37 to 63 nm after a post-annealing treatment at 500 °C for 4 h. Both the current density and ECSA of this post-annealed NPC film were nearly 3 times higher than those of as-prepared NPC film, and the FE toward HCOOH increased from 29 to 45%. X-ray photoelectron spectroscopy and Raman spectroscopy revealed that Cu2O were present on the nanoporous structure, which enhanced the selectivity and FE toward HCOOH in CO2RR. ? 2021 The Electrochemical Society ("ECS"). Published on behalf of ECS by IOP Publishing Limited.
Subjects
Annealing
Carbon dioxide
Copper
Copper oxides
Dealloying
Electrocatalysts
Film preparation
Formic acid
Global warming
Greenhouse gases
Morphology
Nanosheets
X ray photoelectron spectroscopy
Copper films
Electrochemical surface area
Faraday efficiency
Ligament sizes
Morphology behavior
Nano-porous coppers
Nanosheet structure
Postannealing
Reduction reaction
Surface morphology
Type
journal article