Aluminum-magnesium complexes with linearly bridging carbon dioxide
Journal
Angewandte Chemie - International Edition
Journal Volume
44
Journal Issue
45
Pages
7418-7420
Date Issued
2005
Author(s)
Abstract
The linear μ(O,O′) bonding mode of CO2 has been found for the first time in the magnesium–aluminum compounds [{R2Al(μ-NSiMe3)(μ-OSiMe3)Mg(thf)2(μ-O2C)}3] (1 (R=Me) and 2 (R=Et); THF ligands omitted), which were obtained by bubbling CO2 through a mixture of AlR3 and Mg[N(SiMe3)2]2 in THF. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z502400_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Type
journal article