New Imine?Phosphine Palladium Complexes Catalyze Copolymerization of CO?Ethylene and CO?Norbornylene and Provide Well-Characterized Stepwise Insertion Intermediates of Various Unsaturated Substrates
Resource
Organometallics 18 (14): 2574-2576
Journal
Organometallics
Journal Volume
18
Journal Issue
14
Pages
2574-2576
Date Issued
1999
Date
1999
Author(s)
Rajender Reddy, K.
Chen, Chi-Li
Liu, Yi-Hung
Chen, Jwu-Ting
Abstract
New imine−phosphine palladium complexes [Pd(P−N)(CH3)(CH3CN)](BF4) (P−N = o-(diphenylphosphino)-N-benzaldimine derivatives) are synthesized and are found to be active for copolymerization of CO−ethylene and CO−norbornylene, respectively. Stepwise addition of carbon monoxide and various olefins into the new complexes is investigated.
SDGs
Type
journal article
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