Oxazolidinofullerene
Journal
Journal of the Chemical Society, Perkin Transactions 1
Pages
3355-3357
Date Issued
1994
Author(s)
Abstract
The first synthesis of the oxazolidinofullerene 2 has been achieved by cycloaddition of C60with N3CO2Et, followed by the treatment of the product with B Br3at room temperature. The structure of 2 was unambiguously established by spectroscopic means (13C NMR and MS). Methylcyclohexane solutions of aziridinofullerene 1a and oxazolidinofullerene 2 exhibited, at ambient temperature, fluorescence emission at λmax686 and 691 nm, respectively, with vibronic fine structure. The fluorescence lifetimes and quantum yields for 1a and 2 have been measured. © 1994 by the Royal Society of Chemistry. All Rights Reserved.
SDGs
Type
journal article