Atmospheric chemistry-climate feedbacks
Journal
Journal of Geophysical Research
Journal Volume
115
Journal Issue
D12
Date Issued
2010-06
Author(s)
Abstract
We extend the theory of climate feedbacks to include atmospheric chemistry. A change in temperature caused by a radiative forcing will include, in general, a contribution from the chemical change that is fed back into the climate system; likewise, the change in atmospheric burdens caused by a chemical forcing will include a contribution from the associated climate change that is fed back into the chemical system. The theory includes two feedback gains, G che and Gcli. Gche is defined as the ratio of the change in equilibrium global mean temperature owing to long-lived greenhouse gas radiative forcing, under full climate-chemistry coupling, to that in the absence of coupling. Gcli is defined as the ratio of the change in equilibrium mean aerosol or gas-phase burdens owing to chemical forcing under full coupling, to that in the absence of coupling. We employ a climate-atmospheric chemistry model based on the Goddard Institute for Space Studies (GISS) GCM II', including tropospheric gas-phase chemistry, sulfate, nitrate, ammonium, black carbon, and organic carbon. While the model describes many essential couplings between climate and atmospheric chemistry, not all couplings are accounted for, such as indirect aerosol forcing and the role of natural dust and sea salt aerosols. Guided by the feedback theory, we perform perturbation experiments to quantify Gche and Gcli. We find that Gche for surface air temperature is essentially equal to 1.00 on a planetary scale. Regionally, Gche is estimated to be 0.80-1.30. The gains are small compared to those of the physical feedbacks in the climate system (e.g., water vapor, and cloud feedbacks). These values for Gche are robust for the specific model used, but may change when using more comprehensive climate-atmospheric chemistry models. Our perturbation experiments do not allow one to obtain robust values for Gcli. Globally averaged, the values range from 0.99 to 1.28, depending on the chemical species, while, in areas of high pollution, Gcli can be up to 1.15 for ozone, and as large as 1.40 for total aerosol. These preliminary values indicate a significant role of climate feedbacks in the atmospheric chemistry system. Copyright 2010 by the American Geophysical Union.
Subjects
Air pollution; Ammonium compounds; Atmospheric aerosols; Atmospheric temperature; Climate models; Couplings; Feedback; Global warming; Greenhouse gases; Organic carbon; Ozone; Phase equilibria; Water vapor; Aerosol forcing; Atmospheric chemistry model; Black carbon; Chemical change; Chemical species; Chemical systems; Climate system; Feedback gain; Feedback theory; Full coupling; Gas phase chemistry; Gasphase; Global-mean temperature; Planetary scale; Radiative forcings; Sea salt aerosol; Surface air temperatures; Atmospheric chemistry; aerosol; air temperature; atmospheric chemistry; atmospheric modeling; atmospheric pollution; climate modeling; dust; feedback mechanism; gas phase reaction; greenhouse gas; organic carbon; perturbation; radiative forcing; sea salt; surface area; temperature effect; troposphere; water vapor
Type
journal article