Preparation of cis-Mo(CO)2(Ph2P(CH2)nPPh2)2 (n = 1, 2, 3) from cis-dicarbonylbis(norbornadiene)molybdenum and crystal structure of [cis-Mo(CO)2(Ph2P(CH2)3PPh2)2]
Resource
Journal of Organometallic Chemistry 311 (3): 339-347
Journal
Journal of Organometallic Chemistry
Journal Volume
311
Journal Issue
3
Pages
339-347
Date Issued
1986
Author(s)
Abstract
The complexes cis-Mo(CO)2(Ph2P(CH2)nPPh2)2 (n = 1, 2, 3) are synthesized by heating benzene solutions of cis-dicarbonylbis(norbornadiene)molybdenum and the corresponding diphosphines. The X-ray structural analysis of cis-Mo(CO)2(Ph2P(CH2)3PPh2)2 is reported, with the following crystal data: C56H52MoO2P4·2CH2Cl2·0.5C6H14, mol wt. 1189.81, monoclinic, space group P21/n, a 15.643(2), b 21.453(7), c 17.105(3) Å, β 100.75(1)°, V 5639.59 Å3, Z = 4, Dc 1.39, Dm 1.36 g/cm3. © 1986.
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journal article
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