Structure, magnetic ordering, and electrical properties of the CaCu5-derived rare earth-copper-aluminum intermetallics
Date Issued
2005
Date
2005
Author(s)
Wang, Bor-Kai
DOI
en-US
Abstract
We have successfully synthesized two series of rare earth ternary intermetallics RCu4Al and RCu3Al2 (R = Y, La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, and Lu), which crystallized in a CaCu5-derived hexagonal structure with space group P6/mmm as confirmed from the X-ray diffraction measurements. All the samples are single phase except LuCu4Al which possesses both the CaCu5 and the AuBe5 phases. The lattice parameters are deduced from the x-ray patterns, indicating that the unit cell volumes of the RCu4Al and RCu3Al2 compounds have expanded with respect to that of the corresponding RCu5 compounds due to the smaller size of Cu atoms. Besides, a tendency that the Al atom prefers the 3g site of crystal structure in larger-size rare earth compounds and favors the 2c site in smaller-size rare earth compounds is revealed.
Magnetic behavior and electrical resistivity are investigated on these compounds. Curie-Weiss law is used to calculate the effective moments of the rare earth ions in the paramagnetic state, and the Debye temperatures are derived from the resistivity plot. The reisitivity curves of CeCu4Al and CeCu3Al2 are nearly temperature independent in the high temperature range and increase logarithmically with decreasing temperature. The resistivity behaviors of the CeCu4Al and CeCu3Al2 compounds at low temperatures demonstrate both of these two are Kondo systems.
The magnetization and resistivity measurements indicate that almost all the RCu4Al compounds (R = Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm) ordered antiferromagnetically at low temperatures, and for R = Sm, Gd, Tb, and Dy, there exists magnetic reorientation at even lower temperatures. On the other hand, magnetism among the RCu3Al2 compounds is not as abundant as compared to the RCu4Al compounds. A magnetic phase transition at 12 K appears in the SmCu3Al2 compound, and GdCu3Al2 is ferromagnetic below 20 K as revealed both in the magnetization and resistivity measurements. Meanwhile, the TbCu3Al2 and DyCu3Al2 compounds become antiferromagnetic below 6 K and 5.5 K respectively. The Neel temperatures for both the RCu4Al and RCu3Al2 compounds scale with the de Gennes factor which suggests that the primary mechanism of interactions leading to the ordering of the magnetic moments may be the Ruderman-Kittel-Kasuya-Yoshida (RKKY) interaction.
Subjects
稀土合金
電磁性質
rare earth
intermetallics
CaCu5
Type
thesis
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