NITROGEN-CONTAINING TRIPODAL PHOSPHINE LIGANDS
Resource
Phosphorus, Sulfur, and Silicon and the Related Elements 69: 201-211
Journal
Phosphorus, Sulfur, and Silicon and the Related Elements 69: 201-211
Pages
-
Date Issued
1992
Date
1992
Author(s)
Abstract
Abstract Two tripodal phosphine ligands, 2,2-bis(diphenylphosphinomethyl)-1-(diethylamino)propane (P2N) and 2,2-bis(diethylaminomethyl)-1-diphenylphosphinopropane (PN2) were synthesized. Palladium(II) and Platinum(II) complexes with these ligands were obtained from the reaction of PdCl2(CH3CN)2 and K2PtCl4 respectively. Complex (P2N)PtCl2 crystallizes in space group Pca21 with a = 21.983(5), b = 11.419(1), c = 14.179(3) Å, and the structure was refined to R = 0.039 by using 2826 reflections. Key Words: Tripodal ligandsphosphinesnitrogen donorshybrid donorscomplexes
SDGs
Type
journal article
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