Switching luminescent properties in osmium-based β-diketonate complexes
Resource
ChemPhysChem 6 (10): 2012-2017
Journal
ChemPhysChem
Journal Volume
6
Journal Issue
10
Pages
2012-2017
Date Issued
2005
Author(s)
Abstract
Luminescent complexes: Through the design and synthesis of a series of new osmium-based β-diketonate carbonyl complexes (see picture; MLCT=metal-to-ligand charge transfer, kisc=intersystem crossing constant), a remarkable aromatic tunable fluorescence/phosphorescence ratio was explored. The relative luminescent efficiencies and associated dynamics were evaluated. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2267/2005/z500252_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Type
journal article
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