A dual-functional polymer coating on a lithium anode for suppressing dendrite growth and polysulfide shuttling in Li-S batteries
Journal
Chemical Communications
Journal Volume
53
Journal Issue
5
Pages
963-966
Date Issued
2017
Author(s)
Abstract
A surface coating that simultaneously suppressed Li dendrite growth and polysulfide shuttling on a lithium anode was successfully developed using a polymer blend composed of Nafion? and polyvinylidene difluoride (PVDF). This hierarchically nanostructured composite coating efficiently alleviated the swelling and dissolution problems of cation-selective Nafion? in the electrolyte and provided sufficient mechanical strength to accommodate large volumetric variations in the Li anode during charge-discharge cycles. The Nafion?/PVDF-coated Li anode exhibited substantially enhanced rate performance and cyclability as well as improved Coulombic efficiency for Li-S prototype batteries with a high-S-content cathode. ? The Royal Society of Chemistry 2017.
SDGs
Type
journal article