Oxidative cleavage of alkenes catalyzed by a water/organic soluble manganese porphyrin complex
Resource
Tetrahedron 63 (8): 1821-1825
Journal
Tetrahedron
Journal Volume
63
Journal Issue
8
Pages
1821-1825
Date Issued
2007
Author(s)
Abstract
Tetrakis(4-hydroxyphenyl)porphyrin [TPP-(OH)4] was modified with poly(ethylene glycol) chain as four side arms, such that this compound is soluble in both organic and water solutions. Complexation of this porphyrin with manganese metal ions resulted in the formation of MnCl-TPP-(PEO750)4. This complex proved to be an excellent catalyst for the oxidative cleavage of C{double bond, long}C bonds, yielding the corresponding carbonyl compounds with sodium periodate as an oxidant. Mechanistic pathway for this cleavage is discussed. © 2006 Elsevier Ltd. All rights reserved.
SDGs
Type
journal article
File(s)![Thumbnail Image]()
Loading...
Name
45.pdf
Size
180.72 KB
Format
Adobe PDF
Checksum
(MD5):0388c1bc831cadea6d57752d2695a768