Assessing the characteristics of groundwater quality of arsenic contaminated aquifers in the blackfoot disease endemic area
Journal
Journal of Hazardous Materials
Journal Volume
185
Journal Issue
2-3
Pages
1458-1466
Date Issued
2011
Author(s)
Abstract
Redox couples approach and multivariate statistical techniques, including factor analysis, cluster analysis and discriminant analysis, were applied to evaluate and to interpret the complex groundwater quality in the blackfoot disease endemic area, Taiwan. Most groundwater samples were characterized as Na-Ca-HCO3 with HCO3- as the dominant anion. Total arsenic (As) concentration, predominantly as As3+, ranged from <1.0 to 562.7μg/L. The patterns of measured reducing potential were consistent with those values calculated from As couple, revealing the in situ environment enhanced the accumulation of As concentration in the groundwater. Factor analysis proposed a four-factor model, comprising salination, reductive dissolution of Fe/Mn oxyhydroxides, As reduction and chemical potential factor, and explained 89.94% of total variance in groundwater. Furthermore, two factors, reductive dissolution of Fe/Mn oxyhydroxides and As reduction, suggested that the decoupled reductive processes accounted for high As concentration in this area. Cluster analysis was adopted to spatially categorize the sampled wells into three main clusters and characterized by the factor scores of the four-factor model. Two-parameter (pH and Eh) model derived from discriminant analysis can be used for preliminary assessment to determine whether the As concentration exceeds 10μg/L with simple field measurements in this area. ? 2010 Elsevier B.V.
Subjects
Arsenic; Blackfoot disease endemic area; Groundwater; Multivariate statistical techniques; Redox couples approach
Other Subjects
Blackfoot disease; Cluster analysis and discriminant analysis; Contaminated aquifer; Factor analysis; Factor model; Factor scores; Field measurement; Groundwater quality; In-situ; Multivariate statistical techniques; Oxyhydroxides; Preliminary assessment; Redox couple; Reductive dissolution; Reductive process; Salination; Total variance; Aquifers; Arsenic; Chemical analysis; Cluster analysis; Concentration (process); Discriminant analysis; Dissolution; Groundwater pollution; Groundwater resources; Hydrogeology; Sodium; Water quality; Multivariant analysis; arsenic; bicarbonate; calcium; chloride; ferric hydroxide; ground water; iron; magnesium; potassium; sodium; sulfate; aquifer; arsenic; discriminant analysis; endemism; fungal disease; geoaccumulation; groundwater pollution; redox conditions; sampling; water quality; article; blackfoot disease; oxidation reduction reaction; pH; Taiwan; water analysis; water contamination; water quality; Arsenic; Cluster Analysis; Endemic Diseases; Factor Analysis, Statistical; Humans; Oxidation-Reduction; Peripheral Vascular Diseases; Taiwan; Water Pollutants, Chemical; Taiwan
Type
journal article