Tunable magnetic circular dichroism via electrochemically controlled charge-transfer transition in Ru(bpy)32 +aqueous solution
Journal
Applied Physics Letters
Journal Volume
118
Journal Issue
3
Date Issued
2021
Author(s)
Pan H.-P., Huang Y.-H., Hsu H.-S., Lin M.-T.
Abstract
Seeking potential aqueous solution with tunable magnetic properties by applied electrode potentials is an emerging research topic for the integration of aqueous solution into devices. In this work, Ru(bpy)32+, which is widely used for high efficiency electroluminescent and photovoltaic devices, has been demonstrated as a potential liquid electrolyte with tunable magnetic properties by applied electrode potentials evidenced by energy resolved magnetic circular dichroism (MCD) spectroscopy. The MCD signal at 450 nm transforms from paramagnetic to nonmagnetic behavior when the applied electrode potentials are >1.3 V. The transition of the MCD signal from paramagnetic to nonmagnetic behavior is ascribed to the disappearance of metal to ligand charge transfer transition during the electrochemical oxidation process. This work might provide a valuable insight into exploration of functional liquid electrolyte with tunable opto-magnetic properties. ? 2021 Author(s).
Subjects
Charge transfer; Dichroism; Electrochemical electrodes; Electrochemical oxidation; Electrolytes; Magnetic properties; Paramagnetism; Charge transfer transitions; Electrode potentials; Functional liquid; Liquid electrolytes; Magnetic circular dichroism spectroscopy; Magnetic circular dichroisms; Metal to ligand charge transfers; Photovoltaic devices; Circular dichroism spectroscopy
SDGs
Other Subjects
Charge transfer; Dichroism; Electrochemical electrodes; Electrochemical oxidation; Electrolytes; Magnetic properties; Paramagnetism; Charge transfer transitions; Electrode potentials; Functional liquid; Liquid electrolytes; Magnetic circular dichroism spectroscopy; Magnetic circular dichroisms; Metal to ligand charge transfers; Photovoltaic devices; Circular dichroism spectroscopy
Type
journal article