A novel linear-chain material showing sandwiched stacking via alternative Pt(II)⋯Pt(II) or Pt(II)⋯S and π⋯π interactions
Journal
Inorganic Chemistry Communications
Journal Volume
6
Journal Issue
10
Pages
1341-1343
Date Issued
2003
Author(s)
Abstract
A novel linear-chain material, [Pt(8-QNS)2][Pt(terpy)Cl] 2(ClO4)2 (8-QNS = 8-quinolinethiolate; terpy = 2,2′:6′,2″-terpyridine), has been serendipitously isolated and characterized by a crystallographic study. The title compound composed of alternative cationic [Pt(terpy)Cl]+ pairs and [Pt(8-QNS) 2] moieties is formed by an interesting rearrangement process, and it shows sandwiched stacking via alternative Pt(II)⋯Pt(II) or Pt(II)⋯S and π⋯π interactions. © 2003 Elsevier B.V. All rights reserved.
Type
journal article