Chemistry of heterometallic phenyl imido and phosphinidene clusters
Resource
Journal of Cluster Science 3 (3): 333-345
Journal
Journal of Cluster Science
Journal Volume
3
Journal Issue
3
Pages
333-345
Date Issued
1992
Author(s)
Abstract
Triruthenium imido cluster Ru3(CO)10(μ3-NPh)(1) reacts with tungsten hydride LW(CO)3H to afford heterometallic imido clusters LWRu2(CO)8(μ-H) (μ3-NPh), L=Cp, (IIa); L=Cp*, (IIb), whereas the respective phosphinidene complexes LWRu2(CO)8(μ-H)(μ3-PPh), L=Cp, (IXa); L=Cp*, (IXb), were generated via reaction of Ru3(CO)10(μ-H)(μ-PPh2) with CpW(CO)3H and with CP*W(CO)3H followed by thermolysis in the presence of carbon monoxide. Their molecular structure, solution dynamics, and the subsequent reaction with hexafluoro-2-butyne are presented. © 1992 Plenum Publishing Corporation.
Type
journal article