Sinulochmodins A-C, three novel terpenoids from the soft coral Sinularia lochmodes
Resource
Organic Letters 7 (17): 3813-3816
Journal
Organic Letters
Journal Volume
7
Journal Issue
17
Pages
3813-3816
Date Issued
2005
Date
2005
Author(s)
Abstract
An unprecedented C,C-linked dimeric norcembranoid (sinulochmodin A, 1), a novel isocembranoid (sinulochmodin B, 2), and a novel yonarane norditerpenoid (sinulochmodin C, 3) were isolated from the soft coral Sinularia lochmodes. The structures of these metabolites were elucidated by extensive spectroscopic analysis and on the basis of the absolute structures of two related norditerpenoids (4 and 5), which were determined for the first time by a modified Mosher method. A plausible pathway for the biosynthesis of 1 and 3-5 from 2 was postulated. [structure: see text]
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Type
journal article
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