Metal-metal interaction in polynuclear silver(I) complexes: Spectroscopy, luminescent properties and X-ray crystal structure of [Ag3(dppp) 2(MeCN)2(ClO4)2]+ [dppp = bis(diphenylphosphinophenylphosphine)]
Journal
Journal of the Chemical Society, Chemical Communications
Journal Issue
22
Pages
1615-1617
Date Issued
1991
Author(s)
Abstract
The [Ag3(dppp)2(MeCN)2(ClO 4)2]+ complex displays 1(d σ* → pσ) transition at 288 nm and solid state photoluminescence at 467 nm; the Ag-Ag distances are 2.943-3. 014 (2) Å.
Type
journal article