The Study of Electronic and Steric Effects of Platinum Complexes Coordinated by Amino-Imino Bidentate Ligands
Date Issued
2005
Date
2005
Author(s)
Wang, Che-Chun
DOI
zh-TW
Abstract
The dichloroplatinum(II) complexes with the amino-imino ligands have been synthesized successfully by means of substitution reactions of [PtCl2(PhCN)2] and α-amino aldeimines. The dimethylplatinum(II) complexes are synthesized by using [Pt2Me4(μ-SMe2)2] as the starting material. The single crystal crystallographic data indicate that the distance of Pt-N in amino arm is longer than that in imino arm. According to the Pt-C coupling constants, the coordination strength in amino arm appears weaker than that of imino.
Subjects
鉑錯合物
Platinum Complexes
Type
thesis
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